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bold;">3.把純單質(zhì)硅和高純二氧化硅進(jìn)行研磨至微米級以下,二者比例配比混合進(jìn)高溫真空熱解反應系統;</span></strong></p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><strong><span style="font-weight: bold; color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">4.熱解反應形成的一氧化硅(氧化亞硅)進(jìn)行急冷,冷后的氧化亞硅再次研磨至微米級以下;</span></strong></p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><strong><span style="font-weight: bold; color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">5.微米級亞硅與有機碳源、微米純碳等添加劑進(jìn)行配比混合均勻;</span></strong></p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><strong><span style="font-weight: bold; color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">6.配比混合進(jìn)行無(wú)氧熱解炭化包覆氧化亞硅,冷卻包覆后物料再進(jìn)高溫無(wú)氧燒結系統,該次燒結可提高碳包覆氧化亞硅材料密度、硬度等性能;</span></strong></p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><strong><span style="font-weight: bold; color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">7.燒結物料冷卻后三次高溫無(wú)氧燒結,這次燒結使碳包覆氧化亞硅材料提高電導率和電化學(xué)性;</span></strong></p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><strong><span style="font-weight: bold; color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">8.冷卻碳包覆硅氧材料制成微米納米級,該碳包覆硅氧材料經(jīng)產(chǎn)品質(zhì)量檢測后密封包裝外售。<img src="/static/upload/image/20230923/1695449451175131.jpeg" title="1695449451175131.jpeg" alt="默認標題__2023-09-23+14_08_59.jpeg"/></span></strong></p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><span style="color: rgb(0, 0, 0);"><span style="font-size: 19px; font-family: 微軟雅黑; font-weight: bold;">氧化亞硅</span><span style="font-size: 19px; font-family: Arial; font-weight: bold;">SiOx</span><span style="font-size: 19px; font-family: 微軟雅黑; font-weight: bold;">體積膨脹遠小于晶體硅,但仍遠高石墨,因此SiO</span><span style="font-size: 19px; font-family: Arial; font-weight: bold;">x</span><span style="font-size: 19px; font-family: 微軟雅黑; font-weight: bold;">材料研制仍考慮膨脹性問(wèn)題,減少</span><span style="font-size: 19px; font-family: Arial; font-weight: bold;">SiOx</span><span style="font-size: 19px; font-family: 微軟雅黑; font-weight: bold;">循環(huán)中顆粒破碎和粉化,提高材料的循環(huán)壽命,因此納米化也是提升材料的循環(huán)和倍率性能。</span></span></p><p style="margin-top: 0px; margin-bottom: 0px; text-align: left; direction: ltr; unicode-bidi: embed;"><strong><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">該氧硅材料的首次效率僅為63%。為了從本質(zhì)提高SiOx材料的首次效率, Si-SiOx-C復合結構的碳硅負極材料,氧化亞硅納米顆粒表面包覆了一層多孔碳材料,提高了電化學(xué)性能,在0.06C下可逆容量達到1562mAh/g,首次效率達到80%,1C循環(huán)100次,容量保持率可達88%</span></strong></p><p style="margin-top: 0px; margin-bottom: 0px; text-align: left; direction: ltr; unicode-bidi: embed;"><strong><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;"></span></strong></p><p><img src="/static/upload/image/20230923/1695453925830615.jpg" title="1695453925830615.jpg" alt="1695453811731.jpg"/></p><p><strong><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">優(yōu)點(diǎn):  對亞硅碳包覆表面改性,提高亞硅的流動(dòng)性,提高硅材料電導率、首次效率、容量率、膨脹率、循環(huán)性、電化學(xué)及壽命,降低膨脹率。</span></strong></p><p><strong><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 18px;">缺點(diǎn):成本高、首次率略差、膨脹略大、加工性差、循環(huán)差、倍率差。</span></strong></p><p style="margin-top: 0px; margin-bottom: 0px; text-align: left; direction: ltr; unicode-bidi: embed;"><br/></p></div> </div> <div id="8o46e6u" class="baiduShare"> <style type="text/css"> #bdshare { float:right !important; width:180px; } #bdshare span.bds_more, .bds_tools a { line-height:14px; } .baiduShare { margin-bottom:5px; } </style> <!-- Baidu Button BEGIN --> <div class="8qe4soo" id="bdshare" class="bdshare_t bds_tools get-codes-bdshare"> <span id="e6ii4ya" 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